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Theory of Rayleigh-Brillouin optical activity light scattering applicable to chiral liquids.

Robert P CameronEmmanouil I AlexakisAidan S ArnoldDuncan McArthur
Published in: Physical chemistry chemical physics : PCCP (2024)
It has long been understood that dilute samples of chiral molecules such as rarefied gases should exhibit Rayleigh optical activity. We extend the existing theory by accounting for molecular dynamics and correlations, thus obtaining a more general theory of Rayleigh-Brillouin optical activity applicable to dense samples such as neat liquids.
Keyphrases
  • molecular dynamics
  • high resolution
  • density functional theory
  • ionic liquid