Framework Uranyl Silicates: Crystal Chemistry and a New Route for the Synthesis.
Evgeny V NazarchukOleg I SiidraDmitri O CharkinYana G TagirovaPublished in: Materials (Basel, Switzerland) (2023)
To date, uranyl silicates are mostly represented by minerals in nature. However, their synthetic counterparts can be used as ion exchange materials. A new approach for the synthesis of framework uranyl silicates is reported. The new compounds Rb 2 [(UO 2 ) 2 (Si 8 O 19 )](H 2 O) 2.5 ( 1 ), (K,Rb) 2 [(UO 2 )(Si 10 O 22 )] ( 2 ), [Rb 3 Cl][(UO 2 )(Si 4 O 10 )] ( 3 ) and [Cs 3 Cl][(UO 2 )(Si 4 O 10 )] ( 4 ) were prepared at harsh conditions in "activated" silica tubes at 900 °C. The activation of silica was performed using 40% hydrofluoric acid and lead oxide. Crystal structures of new uranyl silicates were solved by direct methods and refined: 1 is orthorhombic, Cmce , a = 14.5795(2) Å, b = 14.2083(2) Å, c = 23.1412(4) Å, V = 4793.70(13) Å 3 , R 1 = 0.023; 2 is monoclinic, C 2/ m , a = 23.0027(8) Å, b = 8.0983(3) Å, c = 11.9736(4) Å, β = 90.372(3) °, V = 2230.43(14) Å 3 , R 1 = 0.034; 3 is orthorhombic, Imma , a = 15.2712(12) Å, b = 7.9647(8) Å, c = 12.4607(9) Å, V = 1515.6(2) Å 3 , R 1 = 0.035, 4 is orthorhombic, Imma , a = 15.4148(8) Å, b = 7.9229(4) Å, c = 13.0214(7) Å, V = 1590.30(14) Å 3 , R 1 = 0.020. Their framework crystal structures contain channels up to 11.62 × 10.54 Å filled by various alkali metals.