σ-Electrons Responsible for Cooperativity and Ring Equalization in Hydrogen-Bonded Supramolecular Polymers.
Lucas de Azevedo SantosDiego CesarioPascal VermeerenStephanie C C van der LubbeFrancesca NunziCélia Fonseca GuerraPublished in: ChemPlusChem (2021)
Invited for this month's cover are collaborators from the TheoCheM group of the Vrije Universiteit Amsterdam and the University of Perugia. The cover picture shows a σ-electron traveling through a hydrogen-bonded squaramide linear chain. The charge transfer within the σ-electronic system is the cause for the cooperativity in the investigated urea, deltamide, and squaramide polymers. More information can be found in the Full Paper by Célia Fonseca Guerra, and co-workers.