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Dilute Semiflexible Polymers with Attraction: Collapse, Folding and Aggregation.

Johannes ZierenbergMartin MarenzWolfhard Janke
Published in: Polymers (2016)
We review the current state on the thermodynamic behavior and structural phases of self- and mutually-attractive dilute semiflexible polymers that undergo temperature-driven transitions. In extreme dilution, polymers may be considered isolated, and this single polymer undergoes a collapse or folding transition depending on the internal structure. This may go as far as to stable knot phases. Adding polymers results in aggregation, where structural motifs again depend on the internal structure. We discuss in detail the effect of semiflexibility on the collapse and aggregation transition and provide perspectives for interesting future investigations.
Keyphrases
  • single molecule
  • climate change
  • liquid chromatography tandem mass spectrometry
  • current status
  • high resolution
  • simultaneous determination
  • gas chromatography