Circularly Polarized Organic Light-emitting Diodes Based on Chiral Hole Transport Enantiomers.

The circularly polarized organic light-emitting diodes (CP-OLEDs) demonstrate promising application in 3D display due to the direct generation of circularly polarized electroluminescence (CPEL). But the chiral luminescence materials face challenges as intricated synthetic route and enantiomeric separation, etc. Herein, we design fresh CP-OLEDs based on chiral hole transport material instead of chiral emitters. A pair of hole transport enantiomers (R/S-NPACZ) exhibit intense dissymmetry factors (|g PL |) about 5.0×10 -3 . With R/S-NPACZ as hole transport layers, CP-OLEDs were fabricated employing six achiral phosphorescence and thermally activated delayed fluorescence (TADF) materials with different wavelengths, in consistence with the generated CPEL spectra. The CP-OLEDs based on achiral red, green and blue iridium(III) complexes exhibit external quantum efficiencies (EQEs) of 14.9%, 30.7% and 14.1% with |g EL | factors of 8.8 × 10 -4 , 2.3 × 10 -3 and 2.0 × 10 -3 , respectively. Moreover, the devices using achiral blue, blueish-green and green TADF materials display EQEs of 24.1%, 17.9% and 25.4% with |g EL | factors of 1.0 × 10 -3 ,3.6 × 10 -3 and 2.2 × 10 -3 , respectively. As far as we know, it is the first example of CP-OLEDs based on chiral hole transport materials, which act as the organic circularly polarizers and have potential to generate CPEL from achiral luminescence materials. This article is protected by copyright. All rights reserved.