Metalloid germanium cluster shears for lanthanide diiodides.

Svetlana V Klementyeva Claudio SchrenkMinghui ZhangMarat M Khusniyarov

Published in: Dalton transactions (Cambridge, England : 2003) (2023)

We report the synthesis and characterization of ionic compounds [(thf) 4 YbI] 2 [Ge 9 (Hyp) 3 ] 2 (1) and [(thf) 5 LnI] 4 [Ge 9 (Hyp) 3 ] 4 (Ln = Eu (2), Sm (3)), (Hyp = Si(SiMe 3 ) 3 ). All compounds were examined by UV-Vis spectroscopy and a blue luminescence of Eu 2+ was found. The solid state magnetic measurements of complexes 2 and 3 confirmed the presence of divalent lanthanides.

Keyphrases

solid state
energy transfer
single molecule
light emitting
molecularly imprinted
room temperature
high resolution
metal organic framework
ionic liquid