Silver-promoted oxidative sulfonylation and ring-expansion of vinylcyclopropanes with sodium sulfinates leading to dihydronaphthalene derivatives.

Silver-promoted sulfonylation and ring-expansion of vinylcyclopropanes with sodium sulfinates is established for the construction of 1-sulfonylmethylated 3,4-dihydronaphthalenes. This sulfonylation process involves a radical pathway, including sulfonyl radical formation, radical addition, ring-opening and cyclization. The 1-sulfonylmethylated 3,4-dihydronaphthalenes can be converted into other useful products.