Photocatalytic Additions of 1-Sulfoximidoyl-1,2-Benziodoxoles to Styrenes.
Han WangDuo ZhangCarsten BolmPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2018)
Sulfoximidoyl-containing 1,2-benziodoxoles add to styrenes by a photoredox radical process affording difunctionalized products with high regioselectivity. The solvent plays a significantly role in the reaction path, in which Eosin Y appears to have a dual role rendering the process diastereoselective.