Reduced Magnetism in Core-Shell Magnetite@MOF Composites.
Sameh K ElsaidiMichael A SinnwellDebasis BanerjeeArun DevarajRavi K KukkadapuTimothy C DroubayZimin NieLibor KovarikMurugesan VijayakumarSandeep ManandharManjula NandasiriB Peter McGrailPraveen K ThallapallyPublished in: Nano letters (2017)
The magnetic susceptibility of synthesized magnetite (Fe3O4) microspheres was found to decline after the growth of a metal-organic framework (MOF) shell on the magnetite core. Detailed structural analysis of the core-shell particles using scanning electron microscopy, transmission electron microscopy, atom probe tomography, and57Fe-Mössbauer spectroscopy suggests that the distribution of MOF precursors inside the magnetic core resulted in the oxidation of the iron oxide core.