A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations.

Sergey A SapchenkoPavel A DemakovDenis G SamsonenkoDanil N DybtsevMartin Schröder Vladimir Petrovich Fedin

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2017)

The metal-organic framework (MOF) complex (H3 O)2 [Zn4 (ur)(Hfdc)2 (fdc)4 ] (1, ur=urotropine, H2 fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb+ and Cs+ optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.

Keyphrases

metal organic framework
loop mediated isothermal amplification
ionic liquid
real time pcr
label free
high resolution
high throughput
heavy metals
high speed
mass spectrometry
mental illness