Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines.

Ritwika RayShubhadeep ChandraVishal YadavPrasenjit MondalDebabrata Maiti Goutam Kumar Lahiri

Published in: Chemical communications (Cambridge, England) (2018)

A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.

Keyphrases

hydrogen peroxide
high intensity
machine learning
room temperature
highly efficient
deep learning
visible light
nitric oxide
transition metal
metal organic framework