Influence of Ni Precursors on the Structure, Performance, and Carbon Deposition of Ni-Al2O3 Catalysts for CO Methanation.

Three Ni-Al2O3 catalysts were prepared, in planetary ball-milling machine, by the mechanochemical method with Al(NO3)3·9H2O as the aluminum precursor, (NH4)2CO3 as the precipitant, and Ni(NO3)2·6H2O, NiCl2·6H2O, and Ni(CH3COO)2·4H2O as nickel precursors (the corresponding catalysts were labeled as Ni-NO, Ni-Cl, and Ni-Ac). The prepared catalysts were characterized by X-ray diffraction (XRD), temperature-programmed reduction (H2-TPR), and N2 adsorption-desorption technologies, and CO methanation performance evaluation was carried out for the catalysts. Results showed that the catalyst with Ni(NO3)2·6H2O as the precursor presented good Ni dispersibility and a small Ni grain size of 6.80 nm. CO conversion, CH4 selectivity, and yield of the catalyst were as high as 78.8, 87.9, and 69.8%, respectively. Carbon deposition analysis from temperature-programmed hydrogenation (TPH) characterization showed that the H2 consumption peak area of the three samples followed the order: Ni-NO (2886.66 au) < Ni-Cl (4389.97 au) < Ni-Ac (5721.65 au), indicating that the Ni-NO catalyst showed higher resistance to carbon deposition, which might be due to its small Ni grain size.