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Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas.

Jie PanHaocong LiKai SunShi TangBing Yu
Published in: Molecules (Basel, Switzerland) (2022)
A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N-C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system's ppm Fe.
Keyphrases
  • visible light
  • high glucose
  • diabetic rats
  • drug induced
  • ionic liquid
  • endothelial cells
  • oxidative stress
  • oxide nanoparticles