Facile synthesis of novel lithium β-diketonate glyme adducts: the effect of molecular engineering on the thermal properties.

Nishant Peddagopu Patrizia Rossi Carmela Bonaccorso Ausrine Bartasyte Paola Paoli Graziella Malandrino

Published in: Dalton transactions (Cambridge, England : 2003) (2020)

Novel adducts of lithium hexafluoroacetylacetonato {Li(hfa)} with polyethers (monoglyme = {CH3OCH2CH2OCH3}, diglyme = {CH3O(CH2CH2O)2CH3}, triglyme = {CH3O(CH2CH2O)3CH3} and tetraglyme {CH3O(CH2CH2O)4CH3} have been synthesized through a single step reaction and characterized by FT-IR spectroscopy, 1H, and 13C NMR, single crystal X-ray diffraction studies along with thermal analysis.

Keyphrases

room temperature
magnetic resonance imaging
solid state
mass spectrometry
single molecule
dual energy