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Crystal structure and Hirshfeld surface analysis of 2-{[7-acetyl-4-cyano-6-hy-droxy-8-(4-meth-oxyphen-yl)-1,6-dimethyl-5,6,7,8-tetra-hydro-isoquinolin-3-yl-]sulfan-yl}acetic acid ethyl ester.

Elham A Al-TaifiIslam S MaraeYasser A El-OssailyShaaban K MohamedJoel T MagueMehmet AkkurtEtify A Bakhite
Published in: Acta crystallographica. Section E, Crystallographic communications (2022)
In the title mol-ecule, C 25 H 28 N 2 O 5 S, (alternative name ethyl 2-{[7-acetyl-4-cyano-6-hy-droxy-8-(4-meth-oxy-phen-yl)-1,6-dimethyl-5,6,7,8-tetra-hydro-isoquinolin-3-yl]sulfanyl}-acetate) the 4-meth-oxy-phenyl group is disposed on one side of the bicyclic core and the oxygen atoms of the hydroxyl and acetyl groups are disposed on the other side. In the crystal, a layered structure parallel to the ac plane is generated by O-H⋯O and C-H⋯O hydrogen bonds plus C-H⋯π(ring) inter-actions.
Keyphrases
  • crystal structure
  • ionic liquid
  • reduced graphene oxide
  • transition metal