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Heteroleptic Tripalladium(II) Cages.

James A FindlayKomal M PatilMichael G GardinerHugo I MacDermott-OpeskinMegan L O'MaraPaul E KrugerDan Preston
Published in: Chemistry, an Asian journal (2022)
There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic Pd II cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, Pd II , and a selection of ditopic ligands of the correct size and geometry.
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