Temperature-Modulated Selective Detection of Part-per-Trillion NO₂ Using Platinum Nanocluster Sensitized 3D Metal Oxide Nanotube Arrays.

Semiconductor chemiresistive gas sensors play critical roles in a smart and sustainable city where a safe and healthy environment is the foundation. However, the poor limits of detection and selectivity are the two bottleneck issues limiting their broad applications. Herein, a unique sensor design with a 3D tin oxide (SnO₂ ) nanotube array as the sensing layer and platinum (Pt) nanocluster decoration as the catalytic layer, is demonstrated. The Pt/SnO₂ sensor significantly enhances the sensitivity and selectivity of NO₂ detection by strengthening the adsorption energy and lowering the activation energy toward NO₂ . It not only leads to ultrahigh sensitivity to NO₂ with a record limit of detection of 107 parts per trillion, but also enables selective NO₂ sensing while suppressing the responses to interfering gases. Furthermore, a wireless sensor system integrated with sensors, a microcontroller, and a Bluetooth unit is developed for the practical indoor and on-road NO₂ detection applications. The rational design of the sensors and their successful demonstration pave the way for future real-time gas monitoring in smart home and smart city applications.