Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds.
Zhiwei XiaoLu WangJunjie WeiChongZhao RanSteven H LiangJingjie ShangGuang-Ying ChenChao ZhengPublished in: Chemical communications (Cambridge, England) (2020)
A novel method has been established for the construction of C-S bonds using redox-active esters with disulfides in the presence of Ru-photoredox catalyst. This method exhibits remarkable functional group tolerance across a wide scope of substrates. Under mild conditions, a structurally diverse array of aryl alkyl sulfides is successfully and efficiently obtained through decarboxylative cross-coupling.