Login / Signup

Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds.

Zhiwei XiaoLu WangJunjie WeiChongZhao RanSteven H LiangJingjie ShangGuang-Ying ChenChao Zheng
Published in: Chemical communications (Cambridge, England) (2020)
A novel method has been established for the construction of C-S bonds using redox-active esters with disulfides in the presence of Ru-photoredox catalyst. This method exhibits remarkable functional group tolerance across a wide scope of substrates. Under mild conditions, a structurally diverse array of aryl alkyl sulfides is successfully and efficiently obtained through decarboxylative cross-coupling.
Keyphrases
  • visible light
  • high glucose
  • electron transfer
  • diabetic rats
  • room temperature
  • high throughput
  • drug induced
  • endothelial cells
  • gold nanoparticles
  • ionic liquid
  • mass spectrometry
  • energy transfer