Coordination-induced spontaneous resolution of a TPPE-based MOF and its use as a crystalline sponge in guest determination.

In this work, by virtue of a coordination-induced fixation of the propeller-like conformation of the tetraphenylethylene (TPE) backbone, we achieved a spontaneous resolution of conglomerate-forming enantiomers of [Co(TPPE)Cl2]·4DMF (1M and 1P), as unambiguously probed by single-crystal X-ray crystallography. Benefitting from the robust, accessible, and electron-rich 1D channels, the chiral MOF turned out to be a good 'crystalline sponge' to adsorb and determine six liquid guests, of which two (2-butanol and 2-butylamine) are crystallized in an enantiospecific manner.