Probing the Local Structure of Na in NaNO 3 -Promoted, MgO-Based CO 2 Sorbents via X-ray Absorption Spectroscopy.

This work provides insight into the local structure of Na in MgO-based CO 2 sorbents that are promoted with NaNO 3 . To this end, we use X-ray absorption spectroscopy (XAS) at the Na K-edge to interrogate the local structure of Na during the CO 2 capture (MgO + CO 2 ↔ MgCO 3 ). The analysis of Na K-edge XAS data shows that the local environment of Na is altered upon MgO carbonation when compared to that of NaNO 3 in the as-prepared sorbent. We attribute the changes observed in the carbonated sorbent to an alteration in the local structure of Na at the NaNO 3 /MgCO 3 interfaces and/or in the vicinity of [Mg 2+ ···CO 3 2- ] ionic pairs that are trapped in the cooled NaNO 3 melt. The changes observed are reversible, i.e., the local environment of NaNO 3 was restored after a regeneration treatment to decompose MgCO 3 to MgO. The ex situ Na K-edge XAS experiments were complemented by ex situ magic-angle spinning 23 Na nuclear magnetic resonance (MAS 23 Na NMR), Mg K-edge XAS and X-ray powder diffraction (XRD). These additional experiments support our interpretation of the Na K-edge XAS data. Furthermore, we develop in situ Na (and Mg) K-edge XAS experiments during the carbonation of the sorbent (NaNO 3 is molten under the conditions of the in situ experiments). These in situ Na K-edge XANES spectra of molten NaNO 3 open new opportunities to investigate the atomic scale structure of CO 2 sorbents modified with Na-based molten salts by using XAS.