A chiral 3D silver(I)-benzenedithiolate coordination polymer exhibiting photoemission and non-linear optical response.
Saly HawilaAhmad AbdallahJean-Luc RukemampunziAlexandra FateevaGilles LedouxRégis DebordStéphane PaihlèsNathalie GuillouFlorian MassuyeauRomain GautierAdel MesbahAude DemessencePublished in: Chemical communications (Cambridge, England) (2022)
A new tridimensional metal-organic chalcogenolate, made of a 1,3-benzenedithiolate bridging ligand and Ag(I), [Ag 2 (1,3-BDT)] n , is reported. This coordination polymer has good thermal stability in air and displays both photoluminescence properties and a second harmonic generation response.