Integration of an N-Heterocyclic Carbene Precursor into a Covalent Triazine Framework for Organocatalysis.

Erik TroschkeKhoa Dang NguyenSilvia PaaschJohannes SchmidtGeorg NickerlIrena Senkovska Eike Brunner Stefan Kaskel

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2018)

The successful incorporation of a thermally fragile imidazolium moiety into a covalent triazine framework resulted in a heterogeneous organocatalyst active in carbene-catalyzed umpolung reaction. The structural integrity of the imidazolium moiety was confirmed by combining solid-state NMR and XPS experiments.

Keyphrases

solid state
ionic liquid
room temperature
solid phase extraction
magnetic resonance
light emitting