Size Effect of MgO on the Ionic Conduction Properties of a LiBH 4 ·1/2NH 3 -MgO Nanocomposite.

A solid-state electrolyte (SSE) is the core component for fabricating solid-state batteries competitive with the currently commercial Li-ion batteries. In the present study, a LiBH 4 ·1/2NH 3 -MgO nanocomposite has been developed as a fast Li-ion conductor. The conductive properties depend strongly on the size of MgO nanopowders. By adding MgO nanoparticles, the first-order transition at 55 °C observed in the crystalline LiBH 4 ·1/2NH 3 is suppressed due to the conversion of LiBH 4 ·1/2NH 3 into the amorphous state. When the size of MgO decreases from 163.6 to 13.9 nm, the MgO amount required for the phase-transition suppression of LiBH 4 ·1/2NH 3 decreases linearly from 92 to 75 wt %, accompanied by a significant enhancement of ionic conductivity. The optimized nanocomposite with 75 wt % MgO of size 13.9 nm exhibits a pronouncedly high conductivity of 4.0 × 10 -3 S cm -1 at room temperature, which is 20 times higher than that of the crystalline LiBH 4 ·1/2NH 3 . Furthermore, a smaller size MgO contributes to a higher electrochemical stability window (ESW) owing to the stronger interfacial interaction via B-O bonds, i.e. , an ESW of 4.0 V is achieved with the addition of 75 wt % MgO of size 13.9 nm.