In situ growth of a GDY-MnO x heterointerface for selective and efficient ammonia production.

The development of new catalysts with high selectivity and efficiency for the electrocatalytic nitrate reduction reaction (NtRR) to produce ammonia (NH 3 ) at room temperature and ambient pressure is still a challenge. Herein, we report a simple in situ growth method for the controlled synthesis of a GDY-MnO x heterointerface by selectively anchoring and growing MnO x on GDY surfaces. Experimental results show that the incomplete charge-transfer between GDY and Mn atoms at the interface structures largely increases the number of active sites, improves the electrical conductivity, and therefore results in excellent electrocatalytic performance for NH 3 synthesis with a maximum FE of 95.4%, an NH 3 yield rate of 463.4 μmol h -1 cm -2 and high long-term stability in 0.1 M KOH + 0.1 M NO 3 - aqueous electrolytes at room temperature and ambient pressure.