Sandwich-Type Polyoxotungstate Consisting of Two Different Trilacunary Keggin-Type Units.

Zhan-Gang HanHui-Xia ZhangDe-Shun ZhangChun-Na LiuRan ZhengGui-Bin XiaXiao-Xiao Wang

Published in: Inorganic chemistry (2016)

A unique mixed W/Sb/Mn/Ag sandwich-type metal-O cluster was isolated, in which the six-membered {Ag4O3[Mn(OH2)]2}2+ cationic belt is sandwiched between two different anionic slices: the trilacunary B-β-[SbW9O33]9- and the central-atom-lost A-α-{[Mn(OH2)]2W7O32}18-.

Keyphrases

room temperature
quantum dots
transition metal
electron transfer
aqueous solution