Electrochemically Deposited Nickel Oxide from Molecular Complexes for Efficient Water Oxidation Catalysis.

A facile method for the electrodeposition of amorphous nickel oxyhydroxide is described and discussed in which well-defined nickel complexes with pyridinedimethanol ligands are employed as single-source molecular precursors. No buffering agent is required to assist the anodic deposition process. The deposited nickel oxyhydroxide shows high robustness and efficiency for electrocatalytic water oxidation.