Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption.

Yun-Wu LiHui YanTong-Liang HuHui-Yan MaDa-Cheng LiSu-Na WangQing-Xia YaoJian-Min DouJian XuXian-He Bu

Published in: Chemical communications (Cambridge, England) (2018)

Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {Fe2Na3}n chains as SBUs, respectively. Both of them exhibit highly selective CO2 adsorption over CH4 and N2, owing to their abundant multiple active sites.

Keyphrases

metal organic framework
aqueous solution
room temperature
wastewater treatment
visible light
carbon dioxide