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Co-existence of five- and six-coordinate iron(II) species captured in a geometrically strained spin-crossover Hofmann framework.

Luonan XuZixi XieKatrina A ZenereJack Kay CleggElise KennyNicole J RijsGuy N L JamesonCameron J KepertBenjamin J PowellSuzanne M Neville
Published in: Dalton transactions (Cambridge, England : 2003) (2022)
Inclusion of an angular bridging ligand, 4,2':6',4''-terpyridine (TPy), into a Hofmann-type framework produces an irregular network in which six- and five-coordinate Fe II species co-exist. The octahedral sites show thermally-induced spin-crossover (SCO) and the rare five-coordinate Fe II sites are high-spin.
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