Synthesis of a monolayer fullerene network.

Two-dimensional (2D) carbon materials, such as graphene, have attracted particular attention owing to the exceptional carrier transport characteristics that arise from the unique π-electron system in their conjugated carbon network structure 1-4 . To complement zero-bandgap graphene, material scientists have devoted considerable effort to identifying 2D carbon materials 5-8 . However, it is a challenge to prepare large-sized single-crystal 2D carbon materials with moderate bandgaps 5,9 . Here we prepare a single-crystal 2D carbon material, namely monolayer quasi-hexagonal-phase fullerene (C 60 ), with a large size via an interlayer bonding cleavage strategy. In this monolayer polymeric C 60 , cluster cages of C 60 are covalently bonded with each other in a plane, forming a regular topology that is distinct from that in conventional 2D materials. Monolayer polymeric C 60 exhibits high crystallinity and good thermodynamic stability, and the electronic band structure measurement reveals a transport bandgap of about 1.6 electronvolts. Furthermore, an asymmetric lattice structure endows monolayer polymeric C 60 with notable in-plane anisotropic properties, including anisotropic phonon modes and conductivity. This 2D carbon material with a moderate bandgap and unique topological structure offers an interesting platform for potential application in 2D electronic devices.