The influence of phosphine ligand substituted [2Fe2S] model complexes as electro-catalyst on proton reduction.

To probe the influence of phosphine ligand substitution on the well-known [2Fe2S] model, two new [FeFe]-hydrogenase model complexes with the phosphine ligands, PMe 3 or P(CH 3 O) 3 , were synthesized, such as μ-(SCH(CH 2 CH 3 )CH 2 S)-Fe 2 (CO) 5 PMe 3 1, and μ-(SCH(CH 2 CH 3 )CH 2 S)-Fe 2 (CO) 5 P(CH 3 O) 3 2 Confirmation of structures was provided by FTIR, 1 H NMR, 13 C NMR, 31 P NMR, elemental analyses and single-crystal X-ray analysis. The crystal structure of complex 2 shows that the P(CH 3 O) 3 ligand has less steric effect on the coordination geometry of the Fe atom than the PMe 3 ligand. In the presence of HOAc in CH 3 CN solution, the hydrogen evolution overpotentials of complexes 1 and 2 were 0.91 V and 0.81 V, respectively. Comparatively, complex 2 produces hydrogen at an overpotential of 0.1 V, lower than that for complex 1. A further electrocatalytic study showed the maximum charges for 1 and 2 were 31.3 mC and 56.3 mC at -2.30 V for 10 min, respectively. These studies showed that the complexes 1 and 2 have the ability, as novel electrocatalysts, for catalysis of hydrogen production, and complex 2 has better electrocatalytic ability than complex 1.