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Crystal structure and Hirshfeld surface analysis of 6-(( E )-2-{4-[2-(4-chloro-phen-yl)-2-oxoeth-oxy]phen-yl}ethen-yl)-4,5-di-hydro-pyridazin-3(2 H )-one.

Said DaouiIsraa MuwafaqEmine Berrin ÇınarAbdulmalik AbuduniaNecmi DegeNoureddine BenchatKhalid Karrouchi
Published in: Acta crystallographica. Section E, Crystallographic communications (2022)
The pyridazine ring in the title compound, C 20 H 17 ClN 2 O 3 , adopts a screw-boat conformation. The whole mol-ecule is flattened, the dihedral angles subtended by the least-squares plane of the central aromatic ring with those of the terminal benzene and pyridazine rings being 15.18 (19) and 11.23 (19)°, respectively. In the crystal, the mol-ecules are linked by pairs of N-H⋯O bonds into centrosymmetric dimers and by C-H⋯π contacts into columns. The results of the Hirshfeld surface analysis show that the most prominent inter-actions are H⋯H, accounting for 36.5% of overall crystal packing, and H⋯O/O⋯H (18.6% contribution) contacts.
Keyphrases
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