Concurrent base and silver(I) catalysis pulsed by fuel acid.

Isa ValiyevAmit GhoshIndrajit PaulMichael Schmittel

Published in: Chemical communications (Cambridge, England) (2022)

Treatment of a crown-ether receptor and a silver(I)-loaded cyclam derivative (NetState-I) with a fuel acid reversibly afforded the protonated cyclam and the silver(I)-loaded crown ether (NetState-II). While NetState-I was catalytically OFF, a base-catalysed Michael addition and a silver(I)-catalysed oxime cyclisation reaction was pulsed under dissipative conditions in NetState-II.

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