Plasma Engineering toward Improving the Microwave-Absorbing/Shielding Feature of a Biomass-Derived Material.

During the past decade, ever-increasing electromagnetic pollution has excited a global concern. A sustainable resource, facile experimental scenario, fascinating reflection loss (RL), and broad efficient bandwidth are the substantial factors that intrigue researchers. This research led to the achievement of a brilliant microwave-absorbing material by treating pampas as biomass. The carbon-based microfibers attained by biowaste were treated by plasma under diverse environments to amplify their microwave-absorbing features. Moreover, a pyrolysis scenario was performed to compare the results. The reductive processes were performed by H 2 plasma and carbonization. However, the CO 2 plasma was performed to regulate the heteroatoms and defects. Interestingly, polystyrene (PS) was applied as a microwave-absorbing matrix. The aromatic rings existing in the absorbing medium establish electrostatic interactions, elevating interfacial polarization, and physical characteristics of PS augment the practical applications of the final product. The manipulated biomasses were characterized by Raman, X-ray diffraction, energy-dispersive spectroscopy, field emission scanning electron microscopy, and diffuse reflection spectroscopy analyses. Eventually, the microwave-absorbing features were estimated by a vector network analyzer. The plasma-treated pampas under H 2 /Ar blended with PS gained a maximum RL of -90.65 dB at 8.79 GHz and an efficient bandwidth (RL ≤ -10 dB) of 4.24 GHz with a thickness of 3.20 mm; meanwhile, plasma treatment under CO 2 led to a maximum RL of 97.99 dB at 14.92 GHz and an efficient bandwidth of 7.74 GHz with a 2.05 mm thickness. Particularly, the biomass plasmolyzed under Ar covered the entire X and K u bands with a thickness of 2.10 mm. Notably, total shielding efficiencies of the treated bioinspired materials were up to ≈99%, desirable for practical applications.