Chalcogenides have attracted great attention as functional materials in optics, electronics, and energy-related applications due to their typical semiconductor properties. Among those chalcogenides, Sb₂S₃ holds great promise in energy storage field, especially as an anode material for alkali metal (Li, Na, and K) batteries. In this work, a one-dimensional coaxial Sb₂S₃@PPy is investigated as a versatile and robust anode in three kinds of alkali metal batteries for the first time, and the energy storage mechanism of these batteries is systematically discussed. As an anode material for sodium ion batteries (SIBs) and potassium ion batteries (KIBs), Sb₂S₃@PPy exhibits high reversible capacity and impressive cycle lifespan. Sb₂S₃@PPy anode demonstrates an adsorption behavior that has a significant influence on its sodium storage behavior, providing a universal model for studying the application of chalcogenide compounds.