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Low field control of spin switching and continuous magnetic transition in an ErFeO 3 single crystal.

Xiaoxuan MaWencheng FanGang ZhaoHaiyang ChenChuankun WangBaojuan KangZhenjie FengJun-Yi GeWei RenShixun Cao
Published in: Physical chemistry chemical physics : PCCP (2022)
The magnetic behavior of a rare-earth orthoferrite ErFeO 3 single crystal can be controlled by low magnetic fields from a few to hundreds of Oe. Here we investigated a high-quality ErFeO 3 single crystal in the temperature range of 5-120 K, with two types of spin switching in the field-cooled-cooling (FCC) and field-cooled-warming (FCW) processes below the temperature of the spin reorientation (SR) transition from Γ 4 to Γ 2 at 98-88 K. The magnitude of the applied magnetic fields can regulate two types of spin switching along the a -axis of the ErFeO 3 single crystal but does not affect the type and temperature range of the SR transition. An interesting "multi-step" type-II spin switching is observed in FCW under low magnetic fields ( H < 18 Oe) just below the SR transition temperature, which is associated with the interaction and the change of magnetic configurations from rare-earth and iron magnetic sublattices. When the magnetic field is lower than 15 Oe, the type-II spin switching in the FCW process gradually changes to a continuous magnetic transition along the a -axis of the ErFeO 3 single crystal. As the magnetic field is reduced to less than 17 Oe, the type-I spin switching in the FCW process also transforms into a continuous magnetic transition. Understanding the magnetic reversal effects will help us explore the potential applications of these magnetic materials for future information devices.
Keyphrases
  • molecularly imprinted
  • room temperature
  • density functional theory
  • transition metal
  • climate change
  • liquid chromatography