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Dynamic [1]rotaxanes via a reversible covalent bond and host-guest anion recognition.

Arico Del MauroZoran KokanVladimír Šindelář
Published in: Chemical communications (Cambridge, England) (2022)
Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate(I) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile.
Keyphrases
  • ionic liquid
  • water soluble