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Crystal structure and Hirshfeld surface analysis of 2-chloro- N -(4-meth-oxy-phen-yl)acetamide.

Mohcine MissiouiWalid GuerrabIntissar NchiouaAbderrazzak El Moutaouakil Ala AllahCamille Kalonji MubengayiAbdulsalam AlsubariJoel T MagueYoussef Ramli
Published in: Acta crystallographica. Section E, Crystallographic communications (2022)
In the title mol-ecule, C 9 H 10 ClNO 2 , the meth-oxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N-H⋯O, C-H⋯O and C-H⋯Cl hydrogen bonds plus C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the inter-molecular inter-actions was performed and indicated that C⋯H/H⋯C inter-actions make the largest contribution to the surface area (33.4%).
Keyphrases
  • crystal structure