Understanding the Role of Silver Nanostructures and Graphene Oxide Applied as Surface Modification of TiO2 in Photocatalytic Transformations of Rhodamine B under UV and Vis Irradiation.

This work is focused on photocatalytic properties of titanium dioxide thin coatings modified with silver nanostructures (AgNSs) and graphene oxide (GO) sheets which were analyzed in processes of chemical transformations of rhodamine B (RhB) under ultraviolet (UV) or visible light (Vis) irradiation, respectively. UV-Vis spectroscopy was applied to analyze the changes in the RhB spectrum during photocatalytic processes, revealing decolorization of RhB solution under UV irradiation while the same process coexisting with the transformation of RhB to rhodamine 110 was observed under Vis irradiation. The novelty of this study is the elaboration of a methodology for determining the parameters characterizing the processes occurring under the Vis irradiation, which enables the comparison of photocatalysts' activity. For the first time, the method for quantification of rhodamine B transformation into rhodamine 110 in the presence of a semiconductor under visible light irradiation was proposed. Photocatalysts with various surface architectures were designed. TiO2 thin coatings were obtained by the sol-gel method. GO sheets were deposited on their surface using the dip-coating method. AgNSs were photogenerated on TiO2 or grown spontaneously on GO flakes. For characterization of obtained photocatalysts, scanning electron microscopy (SEM), X-ray diffraction (XRD) and diffuse-reflectance spectroscopy (DRS) techniques were applied. The results indicate that the surface architecture of prepared coatings does not affect the main reaction path but have an influence on the reaction rates and yields of observed processes.