Rational design of an acceptor-chromophore-relay-catalyst tetrad assembly for water oxidation.
Ramadan Chalil OglouT Gamze Ulusoy GhobadiAytul SaylamDamla BeseCagri BeseHalime Gul YagliogluSalih ÖzçubukçuEkmel OzbayFerdi KaradaşPublished in: Chemical communications (Cambridge, England) (2024)
We report the step-by-step synthesis of a precious metal-free acceptor-chromophore-relay-catalyst tetrad assembly that exhibits a turnover frequency (TOF) of 7.5 × 10 -3 s -1 under neutral conditions. Transient absorption spectroscopic studies indicate that upon fullerenol incorporation into the investigated complexes, charge separation efficiency increases considerably.
Keyphrases
- solar cells
- room temperature
- visible light
- ionic liquid
- highly efficient
- reduced graphene oxide
- carbon dioxide
- metal organic framework
- mass spectrometry
- molecular docking
- energy transfer
- ms ms
- bone mineral density
- hydrogen peroxide
- case control
- cerebral ischemia
- atomic force microscopy
- postmenopausal women
- single molecule