Oligoprolines guide the self-assembly of quaterthiophenes.

Control over the molecular organization of π-conjugated oligothiophenes into different types of supramolecular assemblies is key to their use in organic electronics but difficult to achieve as these chromophores have a pronounced tendency to aggregate. Herein we show that oligoprolines, which do not self-assemble on their own, control the self-assembly of quaterthiophenes. Spectroscopic, microscopic, and diffraction studies with quaterthiophene-oligoproline conjugates revealed the formation of mono- or double-layered sheets or, alternatively, helically twisted ribbons - depending on the length of the oligoproline. The dimensions of the nanoscopic objects, which extend into the micrometer regime, correlate with the molecular dimensions of the quaterthiophene-oligoproline building blocks.