Methane Catalytic Combustion under Lean Conditions over Pristine and Ir-Loaded La 1-x Sr x MnO 3 Perovskites: Efficiency, Hysteresis, and Time-on-Stream and Thermal Aging Stabilities.

The increasing use of natural gas as an efficient, reliable, affordable, and cleaner energy source, compared with other fossil fuels, has brought the catalytic CH 4 complete oxidation reaction into the spotlight as a simple and economic way to control the amount of unconverted methane escaping into the atmosphere. CH 4 emissions are a major contributor to the 'greenhouse effect', and therefore, they need to be effectively reduced. Catalytic CH 4 oxidation is a promising method that can be used for this purpose. Detailed studies of the activity, oxidative thermal aging, and the time-on-stream (TOS) stability of pristine La 1-x Sr x MnO 3 perovskites (LS X M; X = % substitution of La with Sr = 0, 30, 50 and 70%) and iridium-loaded Ir/La 1-x Sr x MnO 3 (Ir/LS X M) perovskite catalysts were conducted in a temperature range of 400-970 °C to achieve complete methane oxidation under excess oxygen (lean) conditions. The effect of X on the properties of the perovskites, and thus, their catalytic performance during heating/cooling cycles, was studied using samples that were subjected to various pretreatment conditions in order to gain an in-depth understanding of the structure-activity/stability correlations. Large (up to ca. 300 °C in terms of T 50 ) inverted volcano-type differences in catalytic activity were found as a function of X, with the most active catalysts being those where X = 0%, and the least active were those where X = 50%. Inverse hysteresis phenomena (steady-state rate multiplicities) were revealed in heating/cooling cycles under reaction conditions, the occurrence of which was found to depend strongly on the employed catalyst pre-treatment (pre-reduction or pre-oxidation), while their shape and the loop amplitude were found to depend on X and the presence of Ir. All findings were consistently interpreted, which involved a two-term mechanistic model that utilized the synergy of Eley-Rideal and Mars-van Krevelen kinetics.