Diffusion of Radical Ions in Ionic Liquids Having Long Alkyl Chains.

Magnetic field effects on a radical ion pair have been studied to investigate the diffusion of the radical ions generated by a photoinduced electron transfer reaction in ionic liquids having short and long alkyl chains. The yield of an escaped radical ion was evaluated by using a nanosecond laser flash photolysis under various magnetic fields. The magnitude of the magnetic field effect on the yield of the escaped radical was linearly increased with increasing solvent viscosity. Such solvent viscosity dependence of the magnetic field effect can be explained with the solvent viscosity dependence of the escape rate of the radical ions from the pair. In the time window (>20 ns) of our measurements, the effect of long alkyl chain aggregation on the dynamics of the radical ions was not clearly observed.