A thiomolybdate cluster for visible-light-driven hydrogen evolution: comparison of homogeneous and heterogeneous approaches.

This study investigates the hydrogen evolution reaction (HER) efficiency of two photosystems incorporating an all-inorganic molecular thiomolybdate [Mo 3 S 13 ] 2- cluster as a HER catalyst. First, we delve into the performance of a homogeneous [Mo 3 S 13 ] 2- /[Ru(bpy) 3 ] 2+ (Mo 3 /Ru) dyad which demonstrates high turnover frequencies (TOFs) and apparent quantum yields (AQYs) at 445 nm approaching the level of 0.5%, yet its performance is marked by pronounced deactivation. In contrast, a heterogeneous approach involves anchoring [Mo 3 S 13 ] 2- onto graphitic carbon nitride (GCN) nanosheets through weak electrostatic association with its triazine/heptazine scaffold. [Mo 3 S 13 ] 2- /GCN (Mo 3 /GCN) displays effective H 2 generation under visible light, with TOF metrics on par with those of its homogeneous analog. Although substantial leaching of [Mo 3 S 13 ] 2- species from the Mo 3 /GCN surface occurs, the remaining {Mo 3 }-based centers demonstrate impressive stability, leading to enduring HER performance, starkly distinguishing it from the homogeneous Mo 3 /Ru photosystem. Photoluminescence (PL) quenching experiments confirm that the performance of Mo 3 /GCN is not limited by the quality of the inorganic interface, but could be optimized by using higher surface area supports or a higher concentration of [Mo 3 S 13 ] 2- sites. Our findings showcase complexities underlying the evaluation and comparison of photosystems comprising well-defined catalytic centers and pave the way for developing analogous surface-supported (photo)catalysts with broad use in energy applications.