Role of SnO 2 Nanoparticles for a Self-Forming Barrier Layer on a Mild Steel Surface in Hydrochloric Acid Medium Containing Piper betle Leaf Extract.

The self-formation of a porous organic thin-film via corrosion inhibitor supports wide applications of carbon steel in industry. Unfortunately, serious damages could be concentrated to the pinhole and/or pore locations in the porous organic film, resulting in the localized corrosion even when an optimal concentration of organic corrosion inhibitors is used. In this work, SnO 2 nanoparticles are used for producing the more robust barrier layer via the self-migration of nanoparticles, resulting in a higher corrosion resistance, smooth and uniform protective layer, as well as the existence of SnO 2 in the protective layer that could directly affect the high inhibition performance. Therefore, the work suggests a new way to make a more robust thin film that could extend the use of organic corrosion inhibitors.