Modern mass spectrometry in atmospheric sciences: Measurement of volatile organic compounds in the troposphere using proton-transfer-reaction mass spectrometry.

Volatile organic compounds (VOCs) in the troposphere are emitted from a wide variety of natural and man-made sources and resulting in environmental issues such as air pollution and climate change. Proton-transfer-reaction mass spectrometry (PTR-MS), a chemical ionization mass spectrometry technique using H3 O+ reagent ions, allows real-time measurements of various VOCs in air with high sensitivity (parts-per-trillion to parts-per-billion level) and fast time response (<1 s). Modern PTR-MS equipped with time-of-flight mass analyzers can measure hundreds of compounds simultaneously. The applications of PTR-MS have greatly promoted understanding VOC sources and their roles in environmental issues, and therefore, PTR-MS has become a well-established analytical technique for in situ VOC measurements in atmospheric sciences. Here, the principles and implementation of PTR-MS are described. We additionally highlight modern PTR-MS techniques for accurate identification and comprehensive quantification of various VOCs. Finally, recent applications for atmospheric science are presented, using examples from research in biomass burning emissions and chemistry.