Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene - redox-controlled generation of a large PAH core.

Søren Lindbæk BromanCecilie Lindholm AndersenTanguy Jousselin-ObaMads MansøOle HammerichMichel FrigoliMogens Brøndsted Nielsen

Published in: Organic & biomolecular chemistry (2018)

Two tetraceno[2,1,12,11-opqra]tetracene-extended tetrathia-fulvalenes were prepared and found to undergo reversible conversion into their planar polycyclic aromatic hydrocarbons (PAHs) upon electrochemical oxidation - at potentials probing the best valence bond representations.

Keyphrases

polycyclic aromatic hydrocarbons
electron transfer
working memory
gold nanoparticles
hydrogen peroxide
ionic liquid
molecular dynamics simulations
molecularly imprinted
mass spectrometry
label free
heavy metals
climate change
drinking water
transition metal