Heterocumulenic carbene nitric oxide radical OCCNO˙.

The elusive heterocumulenic radical OCCNO˙ and its isotopologues OC13CNO˙ and OCC15NO˙ have been prepared by reacting photolytically generated unsaturated carbene OCC/OC13C with ˙NO/15˙NO in cryogenic N2-, Ar-, and Ne-matrices. Upon UV-light (365 nm) irradiation, the C-C bond in OCCNO˙ breaks and yields a long-sought ground-state radical CNO˙ (X2Π), which has also been identified with matrix-isolation infrared spectroscopy.