Hydrogen Bonds Induced Ultra-Long Stability of Conductive Π-d Conjugated FeCo 3 (DDA) 2 with High OER Activity.

Conductive π-d conjugated metal-organic frameworks (MOFs) have attracted wide concerns in electrocatalysis due to their intrinsic high conductivity. However, the poor electrocatalytic stability is still a major problem that hinders the practical application of MOFs. Herein, we report a novel approach to enhancing the stability of MOF-based electrocatalyst, namely, the introduction of hydrogen bonds (H-bonds). Impressively, the π-d conjugated MOF FeCo 3 (DDA) 2 exhibits ultra-high oxygen evolution reaction (OER) stability (up to 2000 h). The experimental studies demonstrate that the presence of H-bonds in FeCo 3 (DDA) 2 is responsible for its ultra-high OER stability. Besides that, FeCo 3 (DDA) 2 also displays a prominent OER activity (an overpotential of 260 mV versus RHE at a current density of 10 mA cm -2 and a Tafel slope of 46.86 mV dec -1 ). Density functional theory (DFT) calculations further indicate that the synergistic effect of the Fe and Co sites in FeCo 3 (DDA) 2 contributes to its prominent OER performance. This work provides a new avenue of boosting the electrocatalytic stability of conductive π-d conjugated MOFs. This article is protected by copyright. All rights reserved.