Studies of the Temperature Dependence of the Structure and Magnetism of a Hexagonal-Bipyramidal Dysprosium(III) Single-Molecule Magnet.
You-Song DingWilliam J A BlackmoreYuan-Qi ZhaiMarcus J GiansiracusaDaniel RetaInigo Vitorica-YrezabalRichard E P WinpennyNicholas F ChiltonYan-Zhen ZhengPublished in: Inorganic chemistry (2021)
The hexagonal-bipyramidal lanthanide(III) complex [Dy(O t Bu)Cl(18-C-6)][BPh 4 ] ( 1 ; 18-C-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane ether) displays an energy barrier for magnetization reversal ( U eff ) of ca. 1000 K in a zero direct-current field. Temperature-dependent X-ray diffraction studies of 1 down to 30 K reveal bending of the Cl-Ln-O t Bu angle at low temperature. Using ab initio calculations, we show that significant bending of the O-Dy-Cl angle upon cooling from 273 to 100 K leads to a ca. 10% decrease in the energy of the excited electronic states. A thorough exploration of the temperature and field dependencies of the magnetic relaxation rate reveals that magnetic relaxation is dictated by five mechanisms in different regimes: Orbach, Raman-I, quantum tunnelling of magnetization, and Raman-II, in addition to the observation of a phonon bottleneck effect.
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