Oxide-on-Oxide Porous Electrodes Revealing Superior Reversible Li + -Coupled Electron-Transfer Properties by Unconventional Heterojunction Effects.
Yosuke HaraRikuo ShigetakeKazuki NakanishiKazuyoshi KanamoriKen SakaushiPublished in: ACS applied materials & interfaces (2022)
Internal spacing of electrodes is a key point for controlling electron-transfer (ET)-related phenomena. However, their disordered porous structures often prevent the observation of microscopic effects. It hampers the development of modern electrochemical theories. The development of model porous electrodes therefore provides an ideal platform to discover intriguing fundamental principles of electrode processes. We developed a new synthetic strategy for all-oxide monolithic ruthenium dioxide (RuO 2 )/antimony-doped tin oxide (ATO) electrodes with a controlled hierarchically porous structure and oxide-oxide heterojunction. The use of the obtained RuO 2 /ATO electrodes as model electrodes suppressed influences related to different mass diffusion efficiencies between electrodes with heterojunctions of different types. Then, we showed unconventional oxide-oxide heterojunction effects, improving reversible Li + -coupled electron-transfer properties using model electrodes constituted of various nanostructured (nano-) RuO 2 on porous ATO. In addition to the superior electrochemical properties of the nano-RuO 2 /ATO heterojunction, the quasi-two-dimensional (2D) RuO 2 /ATO heterojunction led to improved specific capacity at a high rate and longer cycle life. We anticipate that this oxide-oxide heterojunction effect and developed all-oxide model porous electrodes can provide a path to develop advanced reversible energy storage devices.